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The Shapiro reaction or tosylhydrazone decomposition is an organic reaction in which a ketone or aldehyde is converted to an alkene through an intermediate hydrazone in the presence of 2 equivalents of organolithium reagent. [1] [2] [3] The reaction was discovered by Robert H. Shapiro in 1967. [4] The Shapiro reaction was used in the Nicolaou ...
The Philadelphia Premium Outlets is a 553,000-square-foot (51,400 m 2) open-air outlet mall located in Limerick Township, Montgomery County, Pennsylvania, 35 miles northwest of Philadelphia. It is located off an interchange of U.S. Route 422 near the Limerick Nuclear Power Plant. It is owned by the Premium Outlets division of Simon Property Group .
Philip James DeFranco [3] (born Philip James Franchini Jr.; [4] born December 1, 1985), commonly known by his online nickname PhillyD, and formerly known as sxephil, is an American media host and YouTube personality. He is best known for The Philip DeFranco Show, a news commentary show centered on current events in politics and pop culture .
Zone 5 uses eight 2-digit codes (51–58) and two sets of 3-digit codes (50x, 59x) to serve South and Central America. Zone 6 uses seven 2-digit codes (60–66) and three sets of 3-digit codes (67x–69x) to serve Southeast Asia and Oceania. Zone 7 uses an integrated numbering plan; two digits (7x) determine the area served: Russia or Kazakhstan.
In 2011, Dollar Tree achieved total sales of $6.63 billion, opened 278 new stores, and completed a 400,000 square feet (37,000 m 2) expansion of its distribution center in Savannah, Georgia. In 2012, Dollar Tree opened another 345 new stores and exceeded $7 billion in sales, with an end-of-the-year market cap at $9.13 billion.
Shapiro syndrome is an extremely rare disorder consisting of paroxysmal hypothermia (due to hypothalamic dysfunction of thermoregulation ), hyperhydrosis (sweating), and agenesis of the corpus callosum with onset typically on adulthood. The disease affects about 50 people worldwide. The duration and frequency of the episodes vary from person to ...
List of episodes. " Fight Club " is the twentieth episode of the seventh season of the science fiction television series The X-Files. It premiered on the Fox network in the United States on May 7, 2000. It was written by series creator Chris Carter, directed by Paul Shapiro, and featured a guest appearance by Kathy Griffin.
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