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One World Trade Center, also known as One WTC and Freedom Tower, [note 1] is the main building of the rebuilt World Trade Center complex in Lower Manhattan, New York City.. Designed by David Childs of Skidmore, Owings & Merrill, One World Trade Center is the tallest building in the United States, the tallest building in the Western Hemisphere, and the seventh-tallest in the
Tadalafil is an annulated 2,5-diketopiperazine. [25] It is also a 1,2,3,4-tetrahydro-β-carboline. Tadalafil can be synthesized starting from (D)-tryptophan methyl ester and piperonal via a Pictet–Spengler reaction. This is followed by condensations with chloroacetyl chloride and methylamine to complete the diketopiperazine ring: [26]
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