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The protonated form of methadone takes on an extended conformation, while the free base is more compact. In particular, it was found that there is an interaction between the tertiary amine and the carbonyl carbon of the ketone function (R 3 N ••• >C=O) that limits the molecule's conformation freedom, though the distance (291 pm by X-ray ...
The "free-market wing" of economic liberals achieved dominance after the election of Margaret Thatcher as party leader in 1975. Their goal was to reduce the role of the government in the economy and to this end, they supported cuts in direct taxation, the privatisation of nationalised industries and a reduction in the size and scope of the ...
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